Rising stars Luis Figueroa and Christian Alicea also participatede.
Two generations collided when Nieves and Alicia belted out De Mi Enamorate live together.
Later, the music transitioned to Grupo Niche firing up a performance of Una Aventura.
Marc Anthony performs at Footprint Center on Oct. 27, 2024 in PhoenixJohn Medina/Getty Images
Figueroa kept the high-energy going with Tu Me Vuelves Loco.
DLeon then commanded the stage while singing Lloraras, which had Karol G moving in the audience.
Anthony joined in the performance with a stirring rendition of Vivir Lo Nuestro alongside La India.
Sergio George served as the musical director of the all-star performance.
That year, he also took home the Best Tropical Song award for that song.
This years Latin Grammys air live from the Kaseya Center in Miami on Univision and Vix.
